Naturally occurring corrosion inhibitors can slow down the corrosion rate of metals without posing environmental hazards.Vegetable peels have proved beneficial in this regard. Their usage to effectively reduce corrosion rate is an eco- friendly approach which addresses the problem of waste disposal too. This brief review aims to present corrosion mitigation studies by few vegetable peels in different corrosive media and metals.
Introduction
Metal corrosion causes significant structural, aesthetic, and financial damage globally, with annual losses estimated between $700 billion and $1 trillion. Corrosion inhibitors are commonly used to mitigate these effects. Synthetic inhibitors, often containing heteroatoms like nitrogen, phosphorus, oxygen, and sulfur, are effective due to their adsorption properties but can be toxic (e.g., chromates). This has led to increased interest in natural, eco-friendly alternatives derived from plant extracts and waste materials, such as vegetable and fruit peels, which contain phytochemicals and polysaccharides that act as corrosion inhibitors.
Using fruit and vegetable waste as inhibitors supports sustainability and circular economy principles by reducing waste while protecting metals. Various studies have demonstrated high inhibition efficiencies (above 70% to over 95%) for peels from plants like pumpkin, pea, and Vicia faba, applied on metals like carbon steel, aluminium, and mild steel in corrosive environments such as NaCl solutions and acids.
Conclusion
The values of inhibition efficiencies of various vegetable peels indiverse corroding media as well as metals has been tabulated above. Fairly good results can be observed from the table. It can be concluded that vegetable peels can serve a dual purpose of hindering the corrosion process as well as that of waste disposal.
References
[1] Y. Li, Y. Chen, Exploring the potential of plant extracts as corrosion inhibitors: A comprehensive review, Prog. Org. Coatings, 198 (2025) 108915.
[2] Monika, G. Choudhary, Anju, A.Sharma, Impeding Acid corrosion of mild steel using green inhibitor, IJIRSET, 5(12)(2016) 21064-21073.
[3] Shwetha KM, B.M. Praveen, B.K. Devendra, A review on corrosion inhibitors: Types, mechanisms, electrochemical analysis, corrosion rate and efficiency of corrosion inhibitors of mild steel in an acidic environment, Res. Surf. Interfaces 16 (2024) 100258.
[4] H. Cang, Z. Fei, J. Shao, W. Shi, Q.Xu, Corrosion inhibition of mild steel by aloes extract in HCl solution medium, 8 (2013) Int. J. Chem. Sci. 720-734.
[5] A.A. Al -Ameiry, W.N. R. Wan Isahak, W.K. Al-Azzawi, Corrosion Inhibitors: Natural and Synthetic Organic Inhibitors, Lubricants, 11(4) (2023) 174.
[6] A.C. Bastos,M.G. Ferreira, A.M. Simoes, Corrosion inhibition by chromate and phosphate extracts for iron substrates studied by EIS and SVET,Corros. Sci. 48 (2006) 2840-2843.
[7] F.Bentiss, M. Traisenlb, H. Vezin, H.F. Hildebrand, M. Lagrenee, 2,5-Bis (4-dimethylaminophenyl)-1,3,4-oxadiazole and 2,5-Bis (4-dimethylaminophenyl)-1,3,4-thiadiazole as corrosion inhibitors for mild steel in acidic media, Corros. Sci. 46 (2004) 2781-2792.
[8] N.I. Kairi, J. Kassim, The effect of temperature on the corrosion inhibition of mild steel in 1M HCl solution by Curcuma Longa extract, Int. J. Electrochem. Sci. 8 (2013) 7138-7155.
[9] M. Sheydaei, The use of plant extracts as green corrosion inhibitors: A Review, Surfaces 7(2) 380-403.
[10] H. Karahacane, A. Khadraoui, K. Hachama et. al., An overview on plant extracts as potential green corrosion inhibitors for metals and alloys, Arab. J. Chem. Environ. Res. 4(1) (2017) 46–62.
[11] A. Kumar, A. Singh, R. K. Gupta, A.K. Jha, Fruit and vegetable waste management, Current Trends in Horticulture (2024) 148-163.
[12] A.Davarpanah, E. Soroush, B. Ramezanzadeh, Vegetable and Fruit/Fruit Juice Waste as Corrosion Inhibitor. In: Aslam, R., Mobin, M., Aslam, J. (eds) Sustainable Food Waste Management. Materials Horizons: From Nature to Nanomaterials. (2024) doi.org/10.1007/978-981-97-1160-4_8.
[13] S.P. Sha, D. Modak et. al., Fruit waste: a current perspective for the sustainable production of pharmacological, nutraceutical, and bioactive resources, Front. Microbiol., 14 (2023).
[14] E. M. Attia, O. E. Elazabawy, N. S. Hassan, A. M. Hyba, Potato Peel Extract As An Eco-Friendly Corrosion Inhibitor For Carbon Steel In Formation Water, 4(3) (2020) IJARP 51-56.
[15] F.A. Nugroho, J.W. Soedarsono, A Study of Potato Peel Extract (Solanum Tuberosum L) as a green corrosion inhibitor on low carbon steel in a 3.5% NaCl environment, INVOTEK 23 (3) (2024) 187-198.
[16] O.S. Chukwuebuka, The effects of potato peels extract on the inhibition of corrosion and impact strength of mild steel (2014) Experimental Findings, doi:10.13140/rg.2.2.17426.66248.
[17] N. Chaubey, VK Singh, MA Quraishi, Effect of some peel extracts on the corrosion behavior of aluminum alloy in alkaline medium, Int. J. Ind. Chem, 6 (2015) 317-328.
[18] R.D. Alghamdi, L. S. Alqarni, M. Alghamdi, N. F. Alotaibi, H. Gadow, Experimental and Theoretical Investigations on the Use of Pumpkin Peel as a Sustainable Biomass Anticorrosion Agent for Aluminum in HCl Solutions. J. Chem. (2024) 10.1155/2024/5696212.
[19] K. A. Abdelshafeek , W. E. Abdallah, W. M. Elsayed , H. A. Eladawy , A. M. El-Shamy, Vicia faba peel extracts bearing fatty acids moieties as a cost-effective and green corrosion inhibitor for mild steel in marine water: computational and electrochemical studies, Sci. Rep. 12(1) (2022) 20611.